Column solid-phase extraction of sunset yellow and spectrophotometric determination of its use in powdered beverage and confectionery products

Unsal Y. E., SOYLAK M., Tuzen M.

INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, cilt.47, sa.6, ss.1253-1258, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Sayı: 6
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1111/j.1365-2621.2012.02966.x
  • Dergi Adı: INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1253-1258
  • Anahtar Kelimeler: Diaion HP 2MG, powdered beverage and confectionery products, Preconcentration, spectrophotometry, sunset yellow, MULTIWALLED CARBON NANOTUBES, ACTIVATED CARBON, TRACE AMOUNTS, COLORANTS, COPPER, PRECONCENTRATION, REMOVAL, SPECTROMETRY, ADSORBENTS, TARTRAZINE
  • Erciyes Üniversitesi Adresli: Evet

Özet

A new and simple solid-phase extraction method for the determination of trace levels of sunset yellow has been developed on Diaion HP 2MG column system. The adsorbed sunset yellow on the resin was eluted with 3 mL of methanol and determined by UVVis spectrophotometry at 484 nm. Various experimental parameters such as pH, amount of sunset yellow, flow rates of sample and eluent solutions, resin amount, sample volumes, etc. were investigated. The influences of some alkali, alkali earth and transition metals on the recoveries of sunset yellow were investigated. The recovery values for sunset yellow were higher than 95%. Preconcentration factor was found as 150. The detection limit (three sigma) of the reagent blank for sunset yellow was 5.2 mu g L-1. The relative standard deviations (RSD) of the procedure were found as 3.9%. The validation of the presented procedure was performed by the method of standard addition. The procedure was successfully applied to the determination of trace levels of sunset yellow in powdered beverage and confectionery products.