BaTiO3 is a novel adsorbent for solid-phase extraction of copper at trace levels in food and water samples before HR-CS-FAAS detection

Kori A. H., UZCAN F., SOYLAK M.

Journal of Food Composition and Analysis, cilt.122, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 122
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.jfca.2023.105474
  • Dergi Adı: Journal of Food Composition and Analysis
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Analytical Abstracts, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Food Science & Technology Abstracts, Veterinary Science Database
  • Anahtar Kelimeler: Barium titanate, Copper, Determination, Food samples, Water samples
  • Erciyes Üniversitesi Adresli: Evet

Özet

A simple, precise, and rapid method for preconcentration and determination of copper in food and water samples, based on sonication/vortex-free solid phase extraction with high resolution-continuum source flame atomic absorption spectrometry has been developed. In this study, BaTiO3 was synthesized using a single-step hydrothermal method and used as an adsorbent. BaTiO3 was characterized by FT-IR, SEM-EDX, STEM, XRD, and BET methods. The significant feature of the adsorbent is its high surface-to-volume ratio (177.4 m²/g). Important parameters (pH, adsorbent amount, eluent type and volume, adsorption and desorption time, model solution volume, and matrix effects) were optimized. The linear working range (5 – 250 µg L-1) and the detection limit (1.6 µg L-1) were calculated. The presented method was validated with certified reference material and the addition-recovery tests. The application of the method was evaluated for the extraction and determination of Cu(II) in selected food and water samples and quantitative data were obtained.