Crystal structure and Hirshfeld surface analysis of methyl 4 '-amino-3 ',5 '-dicyano-2,2 ''-dioxodispiro[indoline-3,1 '-cyclopentane-2 ',3 ''-indolin]-3 '-ene-5 '- carboximidate with an unknown solvent

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Naghiyev F. N., Khrustalev V. N., Fortalnova E. A., AKKURT M., Khalilov A. N., Bhattarai A., ...More

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.78, pp.665-674, 2022 (ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 78
  • Publication Date: 2022
  • Doi Number: 10.1107/s2056989022005370
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.665-674
  • Keywords: crystal structure, dispiro[cyclopent-3-ene]bisoxindoles, hydrogen bond, Hirshfeld surface analysis, molecular conformation
  • Erciyes University Affiliated: Yes

Abstract

In the title compound, C23H16N6O3, the central five-membered cyclopentene ring adopts an envelope conformation while the five-membered spiro 2,3-dihydro-1H-pyrrole rings exhibit twisted envelope and envelope conformations. One of the 1,3-dihydro-2H-indol-2-one units is in an axial position and the other is in a bisectional position. The methyl methanimidate unit is in an equatorial position. The crystal structure of the title compound is consolidated by intermolecular N-H center dot center dot center dot N, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds, forming a three dimensional network.