SP70-alpha-benzoin oxime chelating resin for preconcentration-separation of Pb(II), Cd(II), Co(II) and Cr(III) in environmental samples

Narin I., Surme Y., Bercin E., Soylak M.

JOURNAL OF HAZARDOUS MATERIALS, cilt.145, ss.113-119, 2007 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 145
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.jhazmat.2006.11.001
  • Dergi Adı: JOURNAL OF HAZARDOUS MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.113-119
  • Anahtar Kelimeler: chelating resin, solid phase extraction, trace metal, flame atomic absorption spectrometry, SOLID-PHASE EXTRACTION, TRACE-METAL IONS, SOLVENT-EXTRACTION, AMBERLITE XAD-2, WATER SAMPLES, MULTIELEMENT PRECONCENTRATION, SPECTROMETRIC DETERMINATION, ONLINE PRECONCENTRATION, ACTIVATED CARBON, NICKEL
  • Erciyes Üniversitesi Adresli: Evet

Özet

In the presented work, a-benzoin oxime immobilized SP70 chelating resin was synthesized for separation and preconcentration of Pb(II), Cd(II), Co(II) and Cr(III). The optimization procedure for analytical parameters including pH, eluent type, flow rate, etc. was examined in order to gain quantitative recoveries of analyte ions. The effects of foreign ions on the recoveries of studied metal ions were also investigated. The detection limits Q(T) were found to be 16.0, 4.2, 1.3, 2.4 mu g L-1 for Pb, Cd, Co and Cr, respectively. The preconcentration factor was 75 for Ph, 100 for Cd, Co and Cr. The optimized method was validated with certified reference materials and successfully applied to the waters, crops and pharmaceutical samples with good results (recoveries greater than 95%, R.S.D. lower than 10%). (c) 2006 Elsevier B.V. All rights reserved.