Ethyl 2-[2-(4-hydroxy-3-methoxybenzylidene)hydrazin-1-ylidene]-3,4- dimethyl-2,3-dihydro-1,3-thiazole-5-carboxylate
Acta Crystallographica Section E: Structure Reports Online, cilt.68, sa.11, 2012 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 68 Sayı: 11
- Basım Tarihi: 2012
- Doi Numarası: 10.1107/s1600536812043772
- Dergi Adı: Acta Crystallographica Section E: Structure Reports Online
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Erciyes Üniversitesi Adresli: Evet
Özet
The title compound, C16H19N3O 4S, is almost planar, with a dihedral angle of 2.88(9)°between the mean planes of the benzene and thiazole rings. The molecule adopts an E conformation about the two C=N bonds, with a C-N-N-C torsion angle of -177.01(11)°. An intramolecular C-H⋯O hydrogen bond exists between a thiazole methyl group and the formic acid ethyl ester carbonyl O atom. In the crystal, molecules are linked by O - H⋯O hydrogen bonds, forming chains propagating along [2-10]. The chains are linked via C-H⋯O hydrogen bonds with R 2 2(12) ring motifs, forming sheets lying parallel to (12-2). The sheets are further linked through out-of-plane C-H⋯N hydrogen bonds with R 2 2(12) ring motifs and C-H⋯π interactions, forming an interesting three-dimensional supramolecular architecture.