Hexakis(thiourea-kappa S)nickel(II) nitrate: a redetermination

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Atıf İçin Kopyala

Monim-ul-Mehboob M., AKKURT M., Khan I. U., Sharif S., Asif I., Ahmad S.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.66, 2010 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 66
• Basım Tarihi: 2010
• Doi Numarası: 10.1107/s1600536810026668
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Erciyes Üniversitesi Adresli: Evet

Özet

A preliminary X-ray study of the title molecular salt, [Ni(CH4N2S)(6)](NO3)(2), has been reported twice previously, by Maar [Acta Cryst. (1961), 14, 894] and Rodriguez, Cubero, Vega, Morente & Vazquez [Acta Cryst. (1961), 14, 1101], using film methods. We confirm the previous studies, but to modern standards of precision and with all H atoms located. The central Ni atom (site symmetry (1) over bar) of the dication is octahedrally coordinated by six S-bound thiourea molecules. The crystal structure is stabilized by intra- and intermolecular N-H...S and N-H...O hydrogen bonds.