Bis(phenanthridinium) hexachloridoplatinate(IV) dimethyl sulfoxide disolvate


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Karaca S., AKKURT M. , Safari N., Amani V., Bueyuekguengoer O., Abedi A.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.65, 2009 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 65
  • Publication Date: 2009
  • Doi Number: 10.1107/s1600536809002736
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Abstract

The asymmetric unit of the title compound, (C(13)H(10)N)(2)-[ PtCl(6)]center dot 2C(2)H(6)OS, contains one independent protonated phenanthridinium cation, half of a centrosymmetric [PtCl(6)](2-) anion and one dimethyl sulfoxide solvent molecule. Intramolecular N-H center dot center dot center dot O and intermolecular C-H center dot center dot center dot Cl hydrogen-bonding interactions seem to be effective in the stabilization of the structure.