Activated Graphite@Nickel Oxide Nanoflowers for the Dispersive Solid-Phase Microextraction (DSPE) of Copper(II) from Water and Food

SOYLAK M., Mohammed A. M. A., ÖZALP Ö.

Analytical Letters, cilt.58, sa.16, ss.2745-2760, 2025 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 58 Sayı: 16
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1080/00032719.2024.2436460
  • Dergi Adı: Analytical Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.2745-2760
  • Anahtar Kelimeler: Activated graphite@NiO nanoflowers, copper, dispersive solid-phase microextraction (DSPE), flame atomic absorption spectrometry (FAAS), food analysis, nanocomposite, water analysis
  • Erciyes Üniversitesi Adresli: Evet

Özet

Activated graphite@NiO nanoflowers was synthetized and characterized by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) and Fourier transform infrared spectrometer (FTIR). It was used as adsorbent for dispersive solid-phase microextraction of Cu(II). The quantitative recovery values were found as pH 8.0, eluent 2.0 M HNO3, vortex time 30 s, adsorbent mass 20 mg, and preconcentration factor 80. The limits of detection and quantification were calculated as 4.23 µg L−1 and 14.1 µg L−1, respectively. The presented method was validated by the analyzing certified reference materials. It was sapplied to determination of copper contents of food and water samples.