Palladium catalyzed Mizoroki-Heck and Suzuki-Miyaura reactions using naphthalenomethyl-substituted imidazolidin-2-ylidene ligands in aqueous media

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AKTAŞ A., AKKOÇ S., GÖK Y.

JOURNAL OF COORDINATION CHEMISTRY, vol.66, no.16, pp.2901-2909, 2013 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 66 Issue: 16
• Publication Date: 2013
• Doi Number: 10.1080/00958972.2013.819092
• Journal Name: JOURNAL OF COORDINATION CHEMISTRY
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.2901-2909
• Erciyes University Affiliated: Yes

Abstract

Naphthalenomethyl-substituted imidazolidinium salts (1a-g) were prepared and characterized by conventional spectroscopic methods, H-1 NMR, C-13 NMR, FTIR, and elemental analysis techniques. The in situ prepared three component systems naphthalenomethyl-substituted imidazolidinium salts, Pd(OAc)(2), and K2CO3 catalyzed quantitatively the Mizoroki-Heck and Suzuki-Miyaura coupling of aryl halides under mild conditions in aqueous media.