Crystal structure and Hirshfeld surface analysis of 3-amino-5-phenylthiazoliain-2-iminium bromide


Creative Commons License

Duruskari G. S. , Khalilov A. N. , AKKURT M. , Mammadova G. Z. , Chyrka T., Maharramov A. M.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.75, ss.1544-1551, 2019 (ESCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 75
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1107/s2056989019013069
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Sayfa Sayıları: ss.1544-1551

Özet

In the cation of the title salt, C9H12N3S+.Br-, the thiazolidine ring adopts an envelope conformation with the C atom adjacent to the phenyl ring as the flap. In the crystal, N-H center dot center dot center dot Br hydrogen bonds link the components into a three-dimensional network. Weak pi-pi stacking interactions between the phenyl rings of adjacent cations also contribute to the molecular packing. A Hirshfeld surface analysis was conducted to quantify the contributions of the different intermolecular interactions and contacts.