A preconcentration procedure for copper, nickel and chromium ions in some food and environmental samples on modified Diaion SP-850

Shokrolahi ., Ghaedi M., Shabani R., Montazerozohori M., Chehreh F., SOYLAK M., ...Daha Fazla

FOOD AND CHEMICAL TOXICOLOGY, cilt.48, sa.2, ss.482-489, 2010 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 48 Sayı: 2
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1016/j.fct.2009.10.040
  • Dergi Adı: FOOD AND CHEMICAL TOXICOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.482-489
  • Anahtar Kelimeler: Diaion SP-850, Preconcentration, Solid phase extraction, Food samples, SOLID-PHASE EXTRACTION, ATOMIC-ABSORPTION-SPECTROMETRY, MODIFIED SILICA-GEL, TRACE-METAL IONS, ONLINE PRECONCENTRATION, CHELATING RESIN, AMBERLITE XAD-2, HEAVY-METALS, WASTE-WATER, SEPARATION
  • Erciyes Üniversitesi Adresli: Evet

Özet

A sensitive and simple method for the simultaneous preconcentration of trace amount of Cu(2+), Ni(2+) and Cr(3+) ions in some real samples has been reported In this method these elements are adsorbed as respective complex with Bis(2-hydroxyacetophenone)-1,2-propanediimine (BHAPPDI) on Diaion SP-850 and the retained metal ions are eluted using 8 ml of 4 M nitric acid. The influences of the analytical parameters including pH, solid phase ingredients amount and condition of eluting solution and sample volume were investigated. The effects of matrix ions on retentions of the analytes were also examined. The recoveries of analytes were generally higher than 90% with a relatively low RSD. The method has been successfully applied for these metal ions contents evaluation in some food and environmental samples. (C) 2009 Elsevier Ltd. All rights reserved.