Synthesis of Polyolefin-g-Poly(ethylene oxide) by Reacting Maleic Anhydride Modified Polypropylene or Poly(propylene-co-ethylene) with Hydroxy-terminated Poly(ethylene Oxide) in the Melt


Ozen I. , Dirnberger K., Rustal C., Fritz H., Eisenbach C. D.

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, cilt.52, ss.101-106, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 52 Konu: 1
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1080/03602559.2012.734357
  • Dergi Adı: POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
  • Sayfa Sayıları: ss.101-106

Özet

The synthesis of amphipolar graft copolymers by reactive extrusion of maleic anhydride modified polypropylene or poly(propylene-co-ethylene) and a, ?-dihydroxy-poly(ethylene oxide) or a-hydro-?-oxymethyl-poly(oxyethylene) was studied. The graft copolymers were characterized by Fourier transform infrared spectroscopy. Residence time of 30 min at 160 degrees C was established to be sufficient for graft copolymer formation by melt extrusion.

The synthesis of amphipolar graft copolymers by reactive extrusion of maleic anhydride modified polypropylene or poly(propylene-co-ethylene) and α, ω-dihydroxy-poly(ethylene oxide) or α-hydro-ω-oxymethyl-poly(oxyethylene) was studied. The graft copolymers were characterized by Fourier transform infrared spectroscopy. Residence time of 30 min at 160°C was established to be sufficient for graft copolymer formation by melt extrusion.