Spectrophotometric determination of basic fuchsin from various water samples after vortex assisted solid phase extraction using reduced graphene oxide as an adsorbent

Tokalıoğlu S., Yavuz E., Aslantas A., Sahan H., Taskin F., Patat Ş.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.149, ss.378-384, 2015 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 149
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1016/j.saa.2015.04.089
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.378-384
  • Anahtar Kelimeler: Reduced graphene oxide, Basic fuchsin, Preconcentration, Fast adsorption and elution, Spectrophotometry, MULTIWALLED CARBON NANOTUBES, ENVIRONMENTAL WATER, MAGNETIC NANOPARTICLES, AQUEOUS-SOLUTION, TRACE AMOUNTS, PRECONCENTRATION, IONS, SORBENT, REMOVAL, NANOCOMPOSITE
  • Erciyes Üniversitesi Adresli: Evet

Özet

In this study, a fast and simple vortex assisted solid phase extraction method was developed for the separation/preconcentration of basic fuchsin in various water samples. The determination of basic fuchsin was carried out at a wavelength of 554 nm by spectrophotometry. Reduced graphene oxide which was used as a solid phase extractor was synthesized and characterized by X-ray diffraction, scanning electron microscopy and the Brunauer, Emmett and Teller. The optimum conditions are as follows: pH 2, contact times for adsorption and elution of 30 s and 90 s, respectively, 10 mg adsorbent, and eluent (ethanol) volume of 1 mL. The effects of some interfering ions and dyes were investigated. The method was linear in the concentration range of 50-250 mu g L-1. The adsorption capacity was 34.1 mg g(-1). The preconcentration factor, limit of detection and precision (RSD, %) of the method were found to be 400, 0.07 mu g L-1 and 1.2%, respectively. The described method was validated by analyzing basic fuchsin spiked certified reference material (SPS-WW1 Batch 114-Wastewater) and spiked real water samples. (C) 2015 Elsevier B.V. All rights reserved.