2-(1-Phenyl-1H-benzimidazol-2-yl)phenol

Creative Commons License

Thiruvalluvar A., Rosepriya S., Jayamoorthy K., Jayabharathi J., YILDIRIM S., Butcher R.

Acta Crystallographica Section E: Structure Reports Online, cilt.69, sa.1, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 69 Sayı: 1
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1107/s1600536812049859
  • Dergi Adı: Acta Crystallographica Section E: Structure Reports Online
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
  • Erciyes Üniversitesi Adresli: Evet

Özet

In the title molecule, C19H14N2O, the benzimidazole unit is close to being planar [maximum deviation = 0.0253 (11) Å] and forms dihedral angles of 68.98 (6) and 20.38 (7)° with the adjacent phenyl and benzene rings; the dihedral angle between the latter two planes is 64.30 (7)°. An intramolecular O - H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by C - H⋯N and C - H⋯O hydrogen bonds, and consolidated into a three-dimensional architecture by π-π stacking interactions, with a centroid-centroid distance of 3.8428 (12) Å.