Crystal structure and Hirshfeld surface analysis of 4-cyano-<i>N</i>-[(4-cyanophenyl)sulfonyl]-<i>N</i>-[2-(5-methylfuran-2-yl)phenyl]benzenesulfonamide

Mammadova G. Z., Yakovleva E. D., Burkin G. M., Khrustalev V. N., AKKURT M., Çelikesir S., ...Daha Fazla

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.79, ss.747-751, 2023 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 79
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1107/s2056989023006254
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI)
  • Sayfa Sayıları: ss.747-751
  • Anahtar Kelimeler: C - H⋯π inter­actions, crystal structure, Hirshfeld surface analysis, hydrogen bonds, sulfonamides, π-π inter­actions
  • Erciyes Üniversitesi Adresli: Evet

Özet

In the title compound, C25H17N3O5S2, intramolecular pi-pi interactions [centroid-to-centroid distance = 3.5640 (9) angstrom] are observed between the furan and benzene rings of the 4-cyanophenyl group. In the crystal, molecules are connected via C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds, forming layers parallel to the (100) plane. These layers are interconnected by C-H center dot center dot center dot pi interactions and weak van der Waals interactions. Hirshfeld surface analysis indicates that H center dot center dot center dot H (30.2%), N center dot center dot center dot H/H center dot center dot center dot N (22.3%), C center dot center dot center dot H/H center dot center dot center dot C (17.9%) and O center dot center dot center dot H/H center dot center dot center dot O (15.4%) interactions make the most significant contributions to the crystal packing.