Separation and Preconcentration of Atrazine on Magnetic Multiwalled Carbon Nanotubes before Determination in Food and Water Samples by High-Performance LIQUID CHROMATOGRAPHY with Diode Array Detection (HPLC-DAD)

UZCAN F., GÜMÜŞ Z. P., SOYLAK M.

Analytical Letters, cilt.56, sa.17, ss.2738-2748, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 56 Sayı: 17
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1080/00032719.2023.2183404
  • Dergi Adı: Analytical Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.2738-2748
  • Anahtar Kelimeler: Atrazine, food samples, high-performance liquid chromatography with diode array detection (HPLC-DAD), magnetic multiwalled carbon nanotubes, preconcentration, water samples
  • Erciyes Üniversitesi Adresli: Evet

Özet

This work focuses upon the easy and efficient synthesis of multi-walled carbon nanotubes (MWCNT) decorated with magnetite used in the vortex-assisted magnetic solid-phase microextraction (VA-m-µ-SPE) of atrazine in water and food samples. The nanocomposite was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and infrared spectroscopy. Parameters that influenced VA-m-µ-SPE (pH, mMWCNT mass, extraction time, eluent type and volume, and sample volume) were optimized. The presented technique provided a preconcentration factor of 10-fold with limits of detection and quantification of 2.1 μg L−1 and 6.4 μg L−1, respectively, and a linear range from 12.5 to 250 μg L−1. VA-m-µ-SPE has been applied in the preconcentration and determination of atrazine in the natural waters. In addition, atrazine was determined in ginger and fennel.