Sorbent extraction of some metal ions on a gas chromatographic stationary phase prior to their flame atomic absorption determinations

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Soylak M., saraçoğlu s., elçi l.

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, cilt.24, sa.5, ss.555-558, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 24 Sayı: 5
  • Basım Tarihi: 2003
  • Doi Numarası: 10.5012/bkcs.2003.24.5.555
  • Dergi Adı: BULLETIN OF THE KOREAN CHEMICAL SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.555-558
  • Anahtar Kelimeler: trace metals, impurities, chromosorb-102, preconcentration, calmagite, NITRATE MEMBRANE-FILTER, AQUEOUS SAMPLES, TRACE AMOUNTS, SPECTROPHOTOMETRIC DETERMINATION, SPECTROMETRIC DETERMINATIONS, AMBERLITE XAD-1180, ACTIVATED CARBON, NATURAL-WATER, PRECONCENTRATION, COPPER
  • Erciyes Üniversitesi Adresli: Evet

Özet

An enrichment/separation system for atomic absorption spectrometric determinations of Cu(II), Fe(III), Ni(II) and Co(II) has been established. The procedure is based on the adsorption of the analytes as calmagite chelates on Chromosorb-102. The effects of some parameters including pH, amount of ligand, salt matrix, flow rates of sample and eluent solutions were investigated. Under optimized conditions, the relative standard deviation of the combined method of sample treatment, preconcentration and determination with FAAS (N=5) is generally lower than 5%. The limit of detection (3sigma) was between 6.0-112.9 mug/L. The results were used for preconcentration of analytes from some sodium and ammonium salt.