Synthesis and crystal structure of catena-poly[[[aqua{2-[(E)-(1-cyano-2-imino-2-methoxy-ethylidene)hydrazinyl]benzenesulfonato}sodium]-di-μ-aqua] dihydrate]

Aliyeva, Vusala; Aliyeva, Fargana; AKKURT, MEHMET; YILDIRIM, SEMA; Bhattarai, Ajaya

doi:10.1107/s2056989023003602

Synthesis and crystal structure of catena-poly[[[aqua{2-[(E)-(1-cyano-2-imino-2-methoxy-ethylidene)hydrazinyl]benzenesulfonato}sodium]-di-μ-aqua] dihydrate]

Atıf İçin Kopyala

Aliyeva V. A., Aliyeva F. S., AKKURT M., YILDIRIM S., Bhattarai A.

Acta Crystallographica Section E: Crystallographic Communications, cilt.79, sa.Pt 5, ss.508-511, 2023 (Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 79 Sayı: Pt 5
Basım Tarihi: 2023
Doi Numarası: 10.1107/s2056989023003602
Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
Derginin Tarandığı İndeksler: Scopus
Sayfa Sayıları: ss.508-511
Anahtar Kelimeler: crystal structure, hydrogen bonds, pi-pi stacking interaction, chain structure, hydrazone
Erciyes Üniversitesi Adresli: Evet

Özet

In the polymeric title compound, {[Na(C10H9N4O4S)(H2O)3]·2H2O}n, sixfold coordinated Na+ cations are linked into a chain parallel to [010] by sharing common water molecules. Next to the four bridging water molecules, each Na+ cation of the chain is bonded to the O atom of a terminal water molecule and an O atom of the SO3- group of the sulfonate anion. Classical O—H· · ·O, O—H· · ·N and N—H· · ·O hydrogen bonds and additional π–π interactions connect these chains into a three-dimensional network.