Metal decorated silica-based core-shell magnetic nanocomposite for the solid-phase microextraction of cadmium(II) with determination by high-resolution continuum source flame atomic absorption spectrometry

JAGIRANI M. S., UZCAN F., SOYLAK M.

INSTRUMENTATION SCIENCE & TECHNOLOGY, vol.50, no.6, pp.637-653, 2022 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 50 Issue: 6
  • Publication Date: 2022
  • Doi Number: 10.1080/10739149.2022.2070919
  • Journal Name: INSTRUMENTATION SCIENCE & TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, BIOSIS, Biotechnology Research Abstracts, Chemical Abstracts Core, Compendex, INSPEC
  • Page Numbers: pp.637-653
  • Keywords: Environmental and tobacco samples, high-resolution continuum source flame atomic absorption spectrometry, metal decorated silica core-shell magnetic nanocomposite, solid-phase microextraction
  • Erciyes University Affiliated: Yes

Abstract

The present study describes a facile and environmentally friendly hydrothermal method for the fabrication of metal decorated silica-based core-shell magnetic nanocomposite M@Si-MNCs, applied as a sustainable coating material for the solid-phase microextraction of toxic cadmium ions. M@Si-MNCs were characterized by scanning electron microscopy, X-ray-diffraction, Fourier transform infrared spectroscopy and Brunauer-Emmett-Teller analyzer. Relevant parameters have been studied to obtain maximum recovery, including pH, adsorbent dosage, model solution volume, - adsorption and desorption time, and matrix effects. The developed method obtained excellent linearity from 50 to 500 mu g/L with a limit of detection of 1.2 mu g/L and a limit of quantification of 4.1 mu g/L. The new method was applied for separation, preconcentration and determination of cadmium in environmental and tobacco samples.