Synthesis, crystal structure and Hirshfeld surface analysis of (2Z,2'E)-2,2'-(3-methoxy-3-phenylpropane-1,2-diylidene)bis(hydrazine-1-carbothioamide) dimethylformamide monosolvate

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Guseinov F. I., Knyazev A. V., Shuvalova E. V., Kobrakov K. I., Samigullina A. I., Atioǧlu Z., ...Daha Fazla

Acta Crystallographica Section E: Crystallographic Communications, cilt.79, ss.910-915, 2023 (ESCI) identifier identifier identifier

Özet

The overall molecular configuration of the title compound, C12H16N6OS2 C3H7NO, is stabilized in the solid state by intramolecular C-HN, C-HO, N-HN and N-HO interactions, forming S(5) ring motifs. In the crystal, molecules are linked to each other and solvent dimethylformamide molecules by N-HS, N-HO, C-HO and C-HS hydrogen bonds, forming a three dimensional network. The phenyl ring of the title compound is disordered over two sites with an occupancy ratio of 0.57 (4):0.43 (4). A Hirshfeld surface analysis was performed to quantify the contributions of the different intermolecular interactions, indicating that the most important contributions to the crystal packing are from HH (38.7%), SH / HS (24.0%), CH / HC (18.5%) and NH / HN (9.8%) interactions.